Which of the following is a characteristic of a trigonal pyramidal geometry?

Prepare for the Semmelweis Chemistry Entrance Exam with focused study sessions using flashcards and multiple choice questions. Each question is designed with explanations and hints to enhance your understanding and readiness for success in the exam!

Trigonal pyramidal geometry is characterized by a central atom surrounded by three substituents (atoms or groups) and one lone pair of electrons. In this arrangement, the three substituents occupy the corners of a pyramid with the central atom at the apex. The presence of the lone pair affects the spatial arrangement, creating a pyramidal shape rather than a flat one, which is typical of trigonal planar arrangements where all substituents are bonded.

For example, ammonia (NH₃) exhibits a trigonal pyramidal geometry due to its three hydrogen atoms bonded to nitrogen and one lone pair of electrons on the nitrogen atom. This lone pair exerts a repulsive force that pushes the hydrogen atoms closer together, resulting in the three-dimensional pyramidal shape.

In contrast, the other choices do not fit this description. One option describes a configuration with four substituents, which corresponds to a tetrahedral geometry. Another involves two substituents and two lone pairs, leading to a bent geometry, while the last option depicts one substituent with three lone pairs, resulting in a linear shape. Therefore, having three substituents and one lone pair distinctly defines the trigonal pyramidal geometry.

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